无机化学课件.pptx

第2章配合物基础和配位立体;一.配合物(complexes;PowerPoint演示文稿;二.常见的配体;双齿配体;六齿配体EDTA;PowerPoint演示文稿;三.配合物的几何构形;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;2024-2-14[Ce(NO;四.配合物的异构现象（反顺，;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;键合异构体(linkagei;五.配位化合物的制备;PowerPoint演示文稿;2024-2-14大環配體配合;PowerPoint演示文稿;六.配合物的制备和表征举例;Cu(dpa)(ppr)2.2;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;第3章.配位场理论和配合物的;一.d轨道在配位场中的能级分;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;部分d4－d7组态ML6配合物;二.?O大小的表征―电子光谱;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;dn组态的光谱项在不同配位场;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;三.电荷迁移光谱（charge;PowerPoint演示文稿;PowerPoint演示文稿;例：OsX62–的吸收峰(L;PowerPoint演示文稿;3d配合物的电子光谱强度;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;例：由下表的配体交换速率常数l;2.平面四方形配合物;反位效應NH3?Cl?反;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;(2).d区元素的LFSE;惰性(inert)配合物;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;二.氧化???原(电子转移)反应;PowerPoint演示文稿;1.外界(球）机理;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;2.内界（球）机理;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;第5章非金属原子簇化合物;PowerPoint演示文稿;PowerPoint演示文稿;硼烷(Borane);PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;二.硼烷中的化学键(定域);PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;三.硼烷的骨架电子对规则(Wa;硼烷结构和骨架电子对数的关系;Wade規則的應用：;四.碳硼烷及金属碳硼烷衍生物;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;PowerPoint演示文稿;P