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ReactionKineticsClaireVallance
1
Reaction Kinetics
Dr Claire Vallance
First year, Hilary term
Suggested Reading
Physical Chemistry, P. W. Atkins
Reaction Kinetics, M. J. Pilling and P. W. Seakins
Chemical Kinetics, K. J. Laidler
Modern Liquid Phase Kinetics, B. G. Cox
Course synopsis
1. Introduction
2. Rate of reaction
3. Rate laws
4. The units of the rate constant
5. Integrated rate laws
6. Half lives
7. Determining the rate law from experimental data
(i) Isolation method
(ii) Differential methods
(iii) Integral methods
(iv) Half lives
8. Experimental techniques
(i) Techniques for mixing the reactants and initiating reaction
(ii) Techniques for monitoring concentrations as a function of time
(iii) Temperature control and measurement
9. Complex reactions
10. Consecutive reactions
11. Pre-equilibria
12. The steady state approximation
13. ‘Unimolecular’ reactions – the Lindemann-Hinshelwood mechanism
14. Third order reactions
15. Enzyme reactions – the Michaelis-Menten mechanism
16. Chain reactions
17. Linear chain reactions
The hydrogen – bromine reaction
The hydrogen – chlorine reaction
The hydrogen-iodine reaction
Comparison of the hydrogen-halogen reactions
18. Explosions and branched chain reactions
The hydrogen – oxygen reaction
19. Temperature dependence of reaction rates
The Arrhenius equation and activation energies
Overall activation energies for complex reactions
Catalysis
20. Simple collision theory
2
1. Introduction
Chemical reaction kinetics deals with the rates of chemical proce
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